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A compilation of radiocarbon measurements is used to characterize deep-sea overturning since the last ice age. 

Abstract The prevailing hypothesis to explain pCO₂rise at the last glacial termination calls upon enhanced ventilation of excess respired carbon that accumulated in the deep sea during the glacial. Recent studies argue lower [O₂] in the glacial ocean is indicative of increased carbon respiration. The magnitude of [O₂] depletion was 100–140 µ mol/kg at the glacial maximum. Because respiration is coupled toδ¹³C of dissolved inorganic carbon (DIC), [O₂] depletion of 100–140 µ mol/kg from carbon respiration would lower deep waterδ¹³C_DICby ∼1‰ relative to surface water. Prolonged sequestration of respired carbon would also lower the amount of¹⁴C in the deep sea. We show that Pacific Deep Waterδ¹³C_DICdid not decrease relative to the surface ocean and Δ¹⁴C was only ∼50‰ lower during the late glacial. Model simulations of the hypothesized ventilation change during deglaciation lead to large increases inδ¹³C_DIC, Δ¹⁴C, andε¹⁴C that are not recorded in observations. 

The geological record encodes the relationship between climate and atmospheric carbon dioxide (CO₂) over long and short timescales, as well as potential drivers of evolutionary transitions. However, reconstructing CO₂beyond direct measurements requires the use of paleoproxies and herein lies the challenge, as proxies differ in their assumptions, degree of understanding, and even reconstructed values. In this study, we critically evaluated, categorized, and integrated available proxies to create a high-fidelity and transparently constructed atmospheric CO₂record spanning the past 66 million years. This newly constructed record provides clearer evidence for higher Earth system sensitivity in the past and for the role of CO₂thresholds in biological and cryosphere evolution. 

Abstract The last deglaciation (~20–10 kyr BP) was characterized by a major shift in Earth's climate state, when the global mean surface temperature rose ~4 °C and the concentration of atmospheric CO₂increased ~80 ppmv. Model simulations suggest that the initial 30 ppmv rise in atmospheric CO₂may have been driven by reduced efficiency of the biological pump or enhanced upwelling of carbon‐rich waters from the abyssal ocean. Here we evaluate these hypotheses using benthic foraminiferal B/Ca (a proxy for deep water [CO₃²⁻]) from a core collected at 1,100‐m water depth in the Southwest Atlantic. Our results imply that [CO₃²⁻] increased by 22 ± 2 μmol/kg early in Heinrich Stadial 1, or a decrease in ΣCO₂of approximately 40 μmol/kg, assuming there were no significant changes in alkalinity. Our data imply that remineralized phosphate declined by approximately 0.3 μmol/kg during Heinrich Stadial 1, equivalent to 40% of the modern remineralized signal at this location. Because tracer inversion results indicate remineralized phosphate at the core site reflects the integrated effect of export production in the sub‐Antarctic, our results imply that biological productivity in the Atlantic sector of the Southern Ocean was reduced early in the deglaciation, contributing to the initial rise in atmospheric CO₂.